Fractal Dimensions of Ceramic Particle Agglomerates Measured Using Polarized Light Scattering

Various ceramic particles were suspended in different non-absorbing solvents such as water and isopropanol. Sonication and surfactants were used to promote dispersion. Results from polarized light scattering measurements on these samples are shown in Figure 1 and Table 1. Slopes of different curves in the figure yield the fractal dimension of corresponding agglomerates. S11-S12 is the light scattered by the agglomerates for a vertically polarized incident light and q is the scattering wave vector.


Figure 1 - Fractal Dimensions of Ceramic Particle Agglomerates from Polarized Light Scattering Measurements

 

Material Refractive Index Dp N N (Range) Df Deff
SiO2 1.46 12 nm 300 100-1600 1.6 80 nm
SiO2 1.46 12 nm 250 100-1600 1.8 76 nm
ZrO 2.40 50 nm 130 25-400 1.8 253 nm

Table 1 - Size Distribution Results for Fractal Agglomerates. Dp is the primary sphere diameter, is the average number of primary spheres in the agglomerate, N is the number of primary spheres, Df is the fractal dimension, and Deff is equivalent sphere size for the agglomerate

 


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